Stereochemistry of Organic Compounds: Principles and ApplicationsWiley, 1991 - 527 pages This text deals with the new concepts and terminology that have been introduced into the treatment of organic stereochemistry over the last decade. Organic reaction mechanisms, as they relate to stereochemistry, are included, and the pericyclic reaction using the frontier molecular orbital approach is explained. The text does not assume a strong grounding in organic chemistry and will therefore be useful to a broader spectrum of students - both graduate and undergraduate. The volume features numerous illustrations and programmed problems. |
Contents
Preface | 1 |
Chapter | 15 |
Definitions and Classifications | 27 |
Copyright | |
17 other sections not shown
Common terms and phrases
absolute configuration achiral acid acyclic addition alcohols Amer angle strain anti antiperiplanar axial axis biphenyls bond angle C₂ carbonyl CH2OH CH3 CH3 chair Chapter Chem chemical shifts chiral centre cis and trans cis isomer CO₂H compounds conformational analysis cyclic cyclohexane diastereomers diastereoselectivity diastereotopic dipole discussed double bond E.L. Eliel effect electron enantiomeric enantiomers enantioselective enantiotopic energy barrier enolate equation equatorial equilibrium erythro Figure formation gauche interactions gives H H H H-bond homotopic hydrogens interconversion ketones kinetic kJ mol ligands meso method methyl mol¹ molecular molecules N.L. Allinger nomenclature nucleophile olefins optically active orbital pair planar plane point group prochiral protons racemic racemisation reaction reagents rearrangement relative configuration respectively ring inversion shown solvent stable stereochemical stereochemistry stereoelectronic stereoisomers stereoselective steric steroids structure substituents substrate symmetry syn elimination temperature Tetrahedron threo torsion angles trans isomer transition twist-boat он созн