Science, Volume 310John Michels (Journalist) Science Company, Moses King, 2005 A weekly record of scientific progress. |
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Page 83
... HPTS ) and acetate ( ̄OAc ) in D2O , Rini et al . have found that tight HPTS ... OAc complexes transfer the deuteron within 150 fs ( time resolution in the experiments ) , whereas encounter complexes formed after mutual dif- fusion ...
... HPTS ) and acetate ( ̄OAc ) in D2O , Rini et al . have found that tight HPTS ... OAc complexes transfer the deuteron within 150 fs ( time resolution in the experiments ) , whereas encounter complexes formed after mutual dif- fusion ...
Page 84
... HPTS in the electronically excited state ( Fig . 1 ) : The decay of the photoacid ( HPTS ) band at 1486 cm - 1 and the simultaneous rise of the conjugate photobase ( HPTS ̄ ) band at 1435 cm - 1 indicate when the deuteron leaves the ...
... HPTS in the electronically excited state ( Fig . 1 ) : The decay of the photoacid ( HPTS ) band at 1486 cm - 1 and the simultaneous rise of the conjugate photobase ( HPTS ̄ ) band at 1435 cm - 1 indicate when the deuteron leaves the ...
Page 85
... HPTS- ... H5O2 + ... -OAc - Cl . We propose that the intermediate complex has a ~ 1 ) hydronium ion with an almost symmetrically hydrogen - bonded Eigen core , where H3O + connects to HPTS with a single hydrogen ectr fined the bond and ...
... HPTS- ... H5O2 + ... -OAc - Cl . We propose that the intermediate complex has a ~ 1 ) hydronium ion with an almost symmetrically hydrogen - bonded Eigen core , where H3O + connects to HPTS with a single hydrogen ectr fined the bond and ...
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