Silicon-Containing Polymers: The Science and Technology of Their Synthesis and ApplicationsR.G. Jones, W. Ando, Julian Chojnowski Springer Science & Business Media, 2013 M11 11 - 768 pages BACKGROUND Polysiloxanes have chains constructed of alternately arranged silicon and oxygen atoms with organic groups attached to the silicon atoms. This structure gives them a unique combination of properties that hold great interest for a host of practical applications. Although they have been known and manufactured for many years, their applications continue to expand rapidly and this boosts progress in the generation of new and modified polysiloxanes. Polysiloxanes constitute the oldf'"' known class of silicon-based polymers and the broadest one when viewed in terms of the variety of structures differing in topology and the constitution of organic substituents. There are also many and various types of siloxane copolymers, some of purely siloxane structure and others of siloxane-organic composition. There is no doubt that polysiloxanes are the most technologically important silicon-based polymers. The broad class of model materials known as silicones is based on polysiloxanes. They are also the best known, as most research in the area of silicon polymers has for many years been directed towards the synthesis of new polysiloxanes, to understanding their properties and to extending their applications. |
Contents
21 | |
2 ORGANOSILOXANE BLOCK AND GRAFT COPOLYMERS | 47 |
4 | 63 |
6 | 70 |
3 SIDE GROUP MODIFIED POLYSILOXANES | 95 |
1 | 105 |
SILICONE COPOLYMER NETWORKS AND INTERPENETRATING POLYMER NETWORKS | 113 |
Interpenetrating Polymer Networks and Copolymer Networks | 115 |
WAXS Measured Crystallisation Kinetics of Polymethylnpropylsilane | 560 |
Thermal Characterisation of Polymethylphenylsilane | 563 |
Structural analysis of Polymethylphenylsilane | 566 |
Conclusions | 571 |
SPECIAL TOPICS Editor W Ando 575 | 574 |
SILICONCONTAINING VINYL MONOMERS AND POLYMERS | 577 |
Polymerisations | 581 |
LIQUID CRYSTALLINE SILICONCONTAINING POLYMERS 593 | 592 |
Silicone Interpenetrating Polymer Networks | 117 |
Silicone Copolymer Networks | 126 |
Other Network Structures | 131 |
Future Trends | 133 |
4 | 134 |
5 PREPARATION AND PROPERTIES OF SILICONE ELASTOMERS 139 | 138 |
Preparation of Silicone Elastomers | 140 |
Elasticity Theories | 141 |
The FloryErman Model | 142 |
StressStrain Behaviour of Silicone Elastomers in the Swollen State | 145 |
Equilibrium Swelling of Silicone Elastomers | 146 |
Tear Strength of Silicone Elastomers | 147 |
Adhesion of Silicone Elastomers to Substrates | 149 |
Stereoregular Siloxane Elastomers | 151 |
6 POLYSILSESQUIOXANES | 157 |
General Considerations in the Preparation of Polysilsesquioxanes | 159 |
Polyphenylsilsesquioxanes | 160 |
Polymethylsilsesquioxanes | 164 |
Other Polysilsequioxanes | 166 |
Cage Silsesquioxanes | 167 |
Structure of polysilsesquioxanes | 175 |
Applications | 178 |
1 | 201 |
4 | 221 |
Future Applications | 229 |
10 POLYCARBOSILANES | 245 |
11 | 297 |
R G Jones 351 | 353 |
PART 1 | 374 |
PART 2 | 401 |
15 MODIFICATION AND FUNCTIONALISATION OF POLYSILANES | 419 |
16 HYDROSILYLATION AND SILYLATION IN ORGANOSILICON | 438 |
SIGMA AND PICONJUGATED ORGANOSILICON POLYMERS | 461 |
18 ELECTRONIC STRUCTURE AND SPECTROSCOPY | 499 |
19 ELECTRONIC AND OPTICAL PROPERTIES IN DEVICE | 531 |
20 THERMAL PROPERTIES AND PHASE BEHAVIOUR OF POLYSILANES | 553 |
Thermal Characterisation of Polymethylnpropylsilane | 555 |
Crystalline Structure of Polymethylnpropylsilane | 557 |
Microstructural Characterisation of Polymethylnpropylsilane | 559 |
Synthesis | 594 |
Polydinalkylsiloxanes | 597 |
Cyclic Siloxanes | 599 |
Silsesquioxanes | 600 |
Ferroelectric Liquid Crystalline Polysiloxanes | 602 |
Elastomeric Networks | 606 |
Characterisation | 608 |
Conclusion | 610 |
MOLECULES WITH MANY POSSIBILITIES | 615 |
Synthesis and Characterisation | 616 |
Functionalisation of Organosilicon Dendrimers | 627 |
Physical Properties and Applications of Organosilicon Dendrimers | 636 |
Conclusions | 639 |
OPTICALLY ACTIVE SILICONCONTAINING POLYMERS 643 | 642 |
Optically Active Polysilanes | 646 |
Other Sicontaining Polymers Polysiloxanes | 657 |
Future Directives | 659 |
HelixHelix Transition in Optically Active Polysilanes | 662 |
25 ORGANOSILICATE OLIGOMERS AND NANOSTRUCTURED MATERIALS | 667 |
The SolGel Process Considered as Inorganic Polymerisation | 668 |
Monosubstituted Systems Silsesquioxanes RSIO1 5 | 671 |
Scope and Limitations | 674 |
Identification | 675 |
The Kinetic Control of the Solid | 679 |
Short Range Organisation in the Solid | 681 |
Control of the Porosity in Silica by Organic Templates | 686 |
Conclusion | 692 |
26 PRECERAMIC POLYMER DERIVED SILICON OXYCARBIDES 697 | 696 |
Synthesis of Silicon Oxycarbide | 699 |
Structure of Silicon Oxycarbide | 709 |
Silicon Oxycarbide Composition Control | 713 |
Reaction Chemistry of Silicon Oxycarbides | 718 |
Applications of Silicon Oxycarbides | 721 |
Summary | 723 |
27 PLASMA PROCESSING OF SILICONCONTAINING MONOMERS | 727 |
28 MICROLITHOGRAPHIC APPLICATIONS OF ORGANOSILICON | 743 |
763 | |
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Common terms and phrases
absorption acid alkyl anionic applications backbone block copolymers bonds carbon carbosilane dendrimers catalyst ceramic CH3 CH3 characterised Chem chemical chemistry chiral chlorosilane co-workers compounds condensation conformation copolymerisation Corriu cross-linked crystalline cyclic dehydrocoupling dendrimers disilenes elastomers electron Equation Figure films formation functional graft copolymers groups high molecular weight hydrolysis hydrosilylation initiator IPNs Lett linear Macromolecules main chain Makromol materials mechanism mesogenic metal methyl molar mass molecular weight molecules monomer observed obtained oligomers oligosilanes optically organic Organomet Organometallics organosilicon oxidation PDMS phase phenyl Phys plasma PMPS polycarbosilanes polycondensation polymer polymer networks polysilanes polysiloxanes precursor prepared properties pyrolysis ratio reaction reactive reported ring-opening polymerisation Si-C Si-H Si-O Si-Si side chains silanes silanol silica silicon atom silicon oxycarbide siloxane silsesquioxane silyl SiOC solid soluble solvent spectra structure studies substituted surface synthesis temperature thermal thermochromic toluene transition vinyl yield