Silicon-Containing Polymers: The Science and Technology of Their Synthesis and ApplicationsR.G. Jones, W. Ando, Julian Chojnowski Springer Science & Business Media, 2001 M11 30 - 768 pages BACKGROUND Polysiloxanes have chains constructed of alternately arranged silicon and oxygen atoms with organic groups attached to the silicon atoms. This structure gives them a unique combination of properties that hold great interest for a host of practical applications. Although they have been known and manufactured for many years, their applications continue to expand rapidly and this boosts progress in the generation of new and modified polysiloxanes. Polysiloxanes constitute the oldf'"' known class of silicon-based polymers and the broadest one when viewed in terms of the variety of structures differing in topology and the constitution of organic substituents. There are also many and various types of siloxane copolymers, some of purely siloxane structure and others of siloxane-organic composition. There is no doubt that polysiloxanes are the most technologically important silicon-based polymers. The broad class of model materials known as silicones is based on polysiloxanes. They are also the best known, as most research in the area of silicon polymers has for many years been directed towards the synthesis of new polysiloxanes, to understanding their properties and to extending their applications. |
Contents
VI | xvii |
VIII | xviii |
IX | xix |
X | xx |
XI | 11 |
XII | 37 |
XIV | 57 |
XV | 62 |
CXV | 421 |
CXVI | 423 |
CXVII | 433 |
CXIX | 443 |
CXX | 448 |
CXXI | 455 |
CXXVI | 479 |
CXXVII | 481 |
XVI | 64 |
XVII | 66 |
XVIII | 68 |
XIX | 73 |
XXII | 74 |
XXIII | 99 |
XXIV | 101 |
XXV | 107 |
XXIX | 109 |
XXX | 111 |
XXXI | 120 |
XXXII | 125 |
XXXIII | 127 |
XXXIV | 133 |
XXXVIII | 134 |
XXXIX | 135 |
XL | 136 |
XLII | 139 |
XLIII | 140 |
XLIV | 141 |
XLV | 143 |
XLVI | 145 |
XLVII | 151 |
LI | 153 |
LII | 154 |
LIII | 158 |
LIV | 160 |
LV | 161 |
LVI | 169 |
LVII | 172 |
LVIII | 179 |
LXI | 180 |
LXII | 188 |
LXIII | 194 |
LXIV | 207 |
LXVIII | 209 |
LXIX | 212 |
LXX | 215 |
LXXI | 216 |
LXXII | 223 |
LXXIII | 227 |
LXXV | 239 |
LXXVI | 241 |
LXXVII | 243 |
LXXVIII | 260 |
LXXIX | 268 |
LXXX | 317 |
LXXXIV | 319 |
LXXXV | 336 |
LXXXVI | 339 |
LXXXVII | 341 |
LXXXVIII | 345 |
XC | 347 |
XCIII | 348 |
XCIV | 351 |
XCV | 354 |
XCVI | 355 |
XCVII | 369 |
XCVIII | 371 |
C | 378 |
CI | 395 |
CVI | 396 |
CVII | 404 |
CVIII | 408 |
CIX | 410 |
CX | 413 |
CXIV | 414 |
CXXVIII | 488 |
CXXIX | 493 |
CXXXIV | 503 |
CXXXV | 518 |
CXXXVI | 525 |
CXLI | 529 |
CXLII | 539 |
CXLIII | 544 |
CXLIV | 547 |
CXLVI | 549 |
CXLVII | 551 |
CXLVIII | 553 |
CXLIX | 554 |
CL | 557 |
CLI | 560 |
CLII | 565 |
CLIII | 569 |
CLV | 571 |
CLVI | 575 |
CLVII | 587 |
CLXI | 588 |
CLXII | 591 |
CLXIII | 594 |
CLXIV | 595 |
CLXV | 596 |
CLXVI | 600 |
CLXVII | 602 |
CLXVIII | 604 |
CLXIX | 609 |
CLXXV | 610 |
CLXXVI | 621 |
CLXXVII | 630 |
CLXXVIII | 633 |
CLXXIX | 637 |
CLXXXII | 640 |
CLXXXIII | 651 |
CLXXXV | 653 |
CLXXXVI | 656 |
CLXXXVII | 661 |
CXC | 662 |
665 | |
CXCII | 668 |
CXCIII | 669 |
CXCIV | 673 |
CXCV | 675 |
CXCVI | 680 |
CXCVII | 686 |
CXCVIII | 691 |
CXCIX | 693 |
CC | 703 |
CCI | 707 |
CCII | 712 |
CCIII | 715 |
CCIV | 717 |
CCV | 721 |
CCIX | 723 |
CCX | 727 |
CCXI | 729 |
CCXII | 732 |
CCXIII | 735 |
CCXIV | 737 |
CCXV | 739 |
CCXVI | 742 |
CCXVII | 752 |
CCXVIII | 757 |
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Common terms and phrases
absorption acid alkyl anionic applications backbone block copolymers bonds carbon carbosilane dendrimers catalyst ceramic CH3 CH3 characterised Chem chemical chemistry chiral chlorosilane co-workers compounds condensation conformation copolymerisation cross-linking crystalline cyclic dehydrocoupling dendrimers disilenes elastomers electron Equation Figure films formation functional functionalised graft copolymers groups helical high molecular weight hydrolysis hydrosilylation initiator IPNs Lett linear Macromolecules main chain Makromol materials mechanism mesogenic metal methyl molar mass molecular weight molecules monomer observed obtained oligomers oligosilanes optically organic Organomet Organometallics organosilicon oxidation PDMS phase phenyl Phys plasma PMPS polycarbosilanes polycondensation polymer polysilanes polysiloxanes precursor prepared properties pyrolysis ratio reaction reactive reagents reported ring-opening polymerisation Scheme Si-C Si-H Si-O Si-Si side chains silanes silanol silicon atom silicon oxycarbide siloxane silsesquioxane silyl SiOC solid soluble solvent spectra structure studies substituted surface synthesis temperature thermal thermochromic toluene transition vinyl yield