Destruction of Hazardous Chemicals in the LaboratoryWiley, 1994 M04 14 - 501 pages Like its groundbreaking predecessor, this Second Edition of Destruction of Hazardous Chemicals offers a collection of detailed procedures that can be used to degrade and dispose of a wide variety of hazardous chemicals. The book has been expanded and updated to broaden the scope of chemicals treated and to include new and modified procedures and alternatives to the use of some highly toxic materials. Entirely new chapters have been added on the removal of metal ions and biological stains from solution and the degradation of mycotoxins, enzyme inhibitors, polycyclic heterocyclic hydrocarbons, and highly reactive reagents such as butyllithium, chlorosulfonic acid, peracids, and phosgene. Another new chapter covers the alternatives to complex metal hydrides in the preparation of super-dry solvents. A new appendix by Dr. Stephen W. Rhodes describes new technologies for the treatment of complex waste streams produced by biomedical research institutions. The procedures described are applicable to both laboratory and bulk quantities, and to solutions in various solvents. Methods for cleaning up spills and solvents for wipe tests to ensure complete surface decontamination are frequently indicated. For laboratory scientists and workers concerned with occupational and environmental safety, this book provides easy reference with a listing of hazardous compounds indexed by name, molecular formula, and CAS registry number. For laboratory administrators, it offers economical alternatives to long-term storage and costly shipping of hazardous chemicals to disposal facilities. |
Contents
Acid Halides and Anhydrides | 17 |
Alkali and Alkaline Earth Metals | 31 |
Aromatic Amines | 47 |
Copyright | |
32 other sections not shown
Common terms and phrases
0.3 M solution acetone acetonitrile add 10 mL add more KMnO4 aflatoxins Agency for Research analyze bromide buffer Carcinogenic Carcinogenic Risk Castegnaro check for completeness Chem chloride chromium(VI citrinin completeness of destruction concentration dacarbazine Decolorize with sodium Destruction Procedures dichloromethane dilute with H2O dimethyl sulfoxide Dissolve equal volume ethidium bromide exceed Exothermic filter to remove g of sodium H₂O hydrazines IARC IARC Monographs International Agency KMnO4 in NaOH KMnO4 solution KOH solution least 1 h Lunn Lyon manganese methanol methyl mg/mL mL of H2O mL of KMnO4 mL of solution mutagenic Mutagenicity Assays NaOH neutralize the filtrate Ni-Al alloy nitrosamines ochratoxin oxidation potassium permanganate Principles of Destruction Refer to safety Research on Cancer Risk of Chemicals rotary evaporator safety considerations section Sansone Sax's Dangerous Properties sodium hypochlorite sodium metabisulfite sodium thiosulfate solution add solution of KMnO4 spill Stir the mixture strongly basic sulfate Water