Page images
PDF
EPUB

That the diamond is a combustible fubftance has been long known; but not having heard of its being burned in atmofpherical, or any other kind of air, I had long withed to do it; and being fupplied by a friend with two fmall ones, I treated them in this manner, and found that near 90 parts in 100 of the air in which they were burned was completely phlogisticated; and the quantity not being fenfibly changed, the remainder was fixed air, which is an effect fimilar to that of heating charcoal of copper in air. The diamonds being very finall, and the quantity of air in which they were burned being fall in proportion, I will not vouch for much exactnefs in the refult. When I get larger diamonds I will endeavour to make the experiment in a more fatisfac. tory manner. Both the diamonds weighed only 3-10ths of a grain, and they loft in the process 15-100 of a grain. The air in which they were burned was 4ths of an ounce measure.

Jos. PRIESTLEY,

To the Editor of the Monthly Magazine.

SIR,

you

PROMISED another letter on the I fubject of the phlogistic theory, and I now fend it. You will find it to confift of mifcellaneous articles, fome of more and others of lefs importance to the decifion of the question that is now before the public. All the letters that I have fent you relate principally to original and recent experiments, to which I have given a good part of the leifure of the laft fummer, and I do not propofe to do any thing more on the fubject till I hear from the great authors and advocates of the theory that I combat in France; and as we have not now any intercourfe with that country, it will probably be a confiderable time

before that can be done.

I am glad, however, to find feveral able advocates of the system in this country; and fome of them, I am confident, will do themfelves honour by their candour, as well as their ability. I am pretty certain, that if due attention be given to the fubject, the controverfy will be decided to general fatisfaction in a very few years. And whenever I fee reafon to think that my opponents have advanced all that they can in anfwer to what I have done and written, I fhall give an account of the impreffion that their obfervations fhall have made on my mind, frecly acknowledging any mistakes into which I may have fallen.

But with my best endeavours to be im

I.

parti, and attentive to every fact that I have ftated, I may have overlooked fome important circumftances relating to them, and have reasoned inconclufively from them. Inflammable air is fometimes procured when one metal is precipitated by another in its metallic ftate. This is a fact that is very eafily explained on the fuppofition that the metal precipitated does not require fo much phlogiflon as that which was diffolved; whereas the doctrine of the decompofition of water cannot, as far as I fee, account for the fact, at leaft in an eafy and natural way.

When zinc is ufed to precipitate lead from a folution of fugar of lead, inflammable air is procured; and according to the phlogistic theory it ought to be fo, fince lead contains much lefs phlogifton than zinc; fo that when the former is revived by means of the latter, it is able to furnifh more than is requifite for the purpose. But if this inflammable air come from the decompofition of the water, the oxygen, which must be developed at the fame time, ought to be found either in the water, or in what remains of the zinc. For it will not be pretended to be in the lead that is revived; and there are no other fubftances prefent. And yet, when I examine this water, I find it entirely free from acidity, and that it yields air much lefs pure than that of the atmosphere.

Iron, I alfo find, will yield more inflammable air by folution in acids than zine; and a faturated folution of iron in the marine acid yields inflammable air by the folution of zinc.

2. In fome of the preceding letters I gave an account of the production of inHammable air from zinc by means of steam, fimilar to that by which the fame kind of air is procured from iron. In this cafe the iron receives a great addition to its weight, which the antiphlogiftians say, arifes from the oxygen corresponding to the hydrogen of the inflammable air, both coming from the decompofition of the water. But as the zinc gains no weight in this process, the refult of the experiment appears to me to be favourable to

the phlogiftic theory, according to which the inflammable air comes from the metal.

This being an experiment of fome confequence, I have lately repeated it, and it may be worth while to recite fome of the particulars of it. Having put an ounce of zinc into an earthen tube, to which I gave a red heat, I made a team pafs over it till I had procured about 300 ounce measures of inflammable air; after which I found the greatest part of the zinc re

duced

duced to a dark coloured femitransparent glafs, adhering pretty clofely to the tube. I was able, however, to feparate them;

and I am confident that the calx did not weigh more than the metal had done, whereas, computing from the proportion of 85 parts of oxygen to 15 of hydrogen (into which it is faid that water is refolvable) it will be found that it ought to have gained about 100 grains. Since then this great proportion of oxygen is not found, either in the calx, or in the water (for this alfo I examined) where will the antiphlogistians fay that we are to look for it? For fince the water, they fay, is decompofed to furnish the inflammable air, it must be fomewhere.

3. I have alfo repeated the experiment of the revival of red precipitate in inflamma. ble air over mercury; obferving particularly that there was neither fixed air, nor any fenfible quantity of water produced, though much inflaminable air difappeared. This air, therefore, muft have entered into the mercury that was revived, and did not unite with any thing that was expelled from the precipitate.

4. It is faid by the antiphlogistians, that spirit of nitre never becomes coloured by imbibing any thing, but always in confequence of giving out oxygen. I think, however, that the contrary is proved by its decompofing nitrous air. But the fame effect is produced, though not in fo remarkable a manner, by means of inflammable air. I put a quantity of dephlogisticated fpirit of nitre into a phial with a ground glais ftopper with inflammable air on its furface; and in another fimilar phial atmospherical air was confined with it. Both of thefe phials I covered with water in inverted glass jars, to prevent their having any communication with the atmosphere. After long expofure in thefe circumftances, that which had the common air on its furface never acquired any colour, or only a very little, from the effect of light tranfmitted through two glasses with water between them; but that on the furface of which the inflammable air was incumbent, acquired colour very foon. I also found, on repeating the experiment, that a part of the inflammable air had been imbibed by the acid. To make this experiment, a phial filled with the acid must be introduced into a jar of inflammable air, and part of it being poured out, the ftopper must be put into it in that fituation. Other precautions must be used which a little experience will teach.

[blocks in formation]

both fixed air and phlogisticated air, from the fame elements, viz. dephlogisticated and inflammable air, or phlogiston; whereas the antiphlogiftians fay that fixed air can only be produced by the union of carbone, or charcoal, with pure air; and that phlogifticated air is a fimple fubftance, called by them azote. I thall, however, mention a few more obfervations which I think fupport what I have advanced on this fubject.

Having made much ufe of a mixture of iron filings and fulphur, for the purpose. of phlogisticating air, I have always had a large quantity which had been long expofed to the atmosphere, from which it is allowed that it attracts nothing befides dephlogifticated air. Of this mixture, then quite dry and brown, 31⁄2 ounces expofed to heat in an earthen tube gave 120 ounce measures of air, of which about one tenth was fixed air, and the rest almost wholly phlogifticated. Both these kinds of air, therefere, muft confift of dephlogifticated air from the atmosphere, and fomething contained in the iron or fulphur, both of which are maintained to be fimple fubftances. There remained a black powder ftrongly attracted by the magnet.

6. In general, iron filings and fulphur immerfed in mercury or water, or placed in a vacuum, yield inflammable air; but in fome cafes (though I do not know the reafon of the difference) this mixture has yielded phlogifticated air. Having placed a pot containing this mixture in a vacuum, I found, after fome days, that it had yielded

ounce measures of air; and examining it I found it to be completely phlogisti cated. I then put the fame mixture under water, and placing it near the fire, it gave an ounce meature more, all phlogi.ticated.

At another time, two ounce measures of air was yielded by a mixture of this kind, and being examined long after it was formed, it was found to be wholly phlogifticated. It might, however, have been inflammable air which had undergone that change.

7. From a quantity of calx of lead, part grey and part yellow, in a glass tube, I got about its bulk of almoft pure fixed air; and the refiduum extinguished a candle. Where could be the carbone in this cafe?

8. A folution of copper in volatile alkali, gave phlogifticated air with the marine acid; and it will not be easy to fay where this azote existed before the process.

9. It is generally thought that the fixed air contained in fallen lime has been attracted from the atmosphere, in which

is

is faid to float in a loose uncombined ftate. But from no other experiment that I am acquainted with can it be proved that any fixed air neceffarily exifts in the atmof phere, and lime, and lime water, will acquire it in all fituations. I am therefore inclined to think that this fixed air is compofed of phlogifton imparted to the lime from the fire to which it had been expofed, and the dephlogisticated air in the atmofphere; and I have always found that a portion of atmospherical air expofed fome time to lime or lime water, is fenfibly lefs pure than before; fome part of the dephlogisticated air of which it is compofed having been taken from it by the lime; and it is never found again except as a component part of the fixed air which is afterwards expelled from it.

The fixed air which is expelled from the yellow calx of lead, which has been fome time expofed to the atmosphere, has, I doubt not, the fame fource. For when it is heated presently after it is made, little or no air can be expelled from it, as it may

some time afterwards. And I find that this fubftance alfo expofed to a portion of atmospherical air, makes it lefs pure than it was before, just as in the cafe of quick lime.

.IO. That phlogifticated air is fometimes produced from the uniting of dephlogifticated air in the atmosphere, and phlogifton in the fubftances exposed to it, I think I have fufficiently proved. I fhall, however, just mention another experiment, which is easily repeated, and which I think demonftrates the fame thing. It is well known that hot charcoal imbibes any kind of air, and I have obferved that when it is afterwards put into water it gives this air out again. But if the air be that of the atmofphere, it takes the dephlogisticated part in preference to the other, leaving the remainder phlogisticated; and the air that it gives out after this in water, is chiefly phlogifticated alfo. What then becomes of the dephlogisticated air that has difappeared? Will it be faid that it remains in the charcoal which had imbibed it? Whence then, came the purified air which it gave out; when, according to the new theory, charcoal does not contain any fuch principles. It is not found in the water into which it is put ; for this gives out air less pure than it did before the procefs.

Before the new theory of chemistry can be unexceptionably established, the following things must be done.-Whenever inflammable air or hydrogen is procured, evidence must be given of the production of a due proportion of oxygen about 85

of this to 15 of the other, and this evidence must be fomething more than an addition of weight to any thing. It must be either actual acidity, or deplogisti cated air, otherwife there is no proof of the inflammable air coming from the decompo fition of water. This, however, has not yet been done with respect to iron, or any other fubftance by means of which inflammable air is procured.

II. When water is procured by the burning of inflammable air in dephlogisticated air, the water must not only be free from acidity, but there must be no production of phlogisticated air in the process. For by the decompofition of this air nitrous acid may be procured. I am, dear Sir, Northumberland, Yours fincerely, Jan. 17, 1799. J. PRIESTLEY,

To the Editor of the Monthly Magazine.

SIR,

Aare defolating many other coun-
Ta time when the ravages of war

tries, it is not an unpleafing contraft to
fee in our own, trade flourishing, and
towns, in confequence, fpringing up in
places where before exifted only a few
fcattered houses. I was led to this re-
flection by paffing through a town very
lately, in the midland parts of Wales,
which twenty years ago deferved fcarcely
the name of a village. As the means by
which it has increased in numbers and
opulence cannot but be interefting, I
fend you this fhort account of the cir-
cumftance; and leave it to you, to infert
it or not, as you think proper, in your
Monthly Mifcellany.

The town I allude to is called Myrthertedvel, fituated on the borders of Breconfhire, next to the county of Glamorgan. The Ipot on which it stands, and the immediate neighbourhood, was the fortunate purchase of a gentleman, who does not feem fully aware of its value. It coft him only eight hundred pounds; and, in ground-rents alone, he now lets it out for more than the yearly rent of one thoufand pounds.

As the town is fituated in a barren diftrict, and fupported folely by the iron trade, which the owner deems precarious, he is averfe to letting out any more on building leafes; as it is only fuffering, he thinks, malons to lay ftones and mortar on his eftate, for him, in fome future time to remove.

This is acting upon a very narrow policy indeed, and may be the means of cramping the rifing spirit of

the

the place. Not the prefent owner, nor many generations after him, will fee the value of eftates leffen in this neighbourhood, fince the furrounding hills are compofed of little elle but coal and ore; and, before any fuch depreciation can take place, muft literally be removed.

The whole district, where these minerals abound, extends about eight miles in length, and four in breadth. Two ranges of hills bound this space, having a valley betwixt them; in which ftands the town of Myrther.

The first person who difcovered mines in these parts, and determined to work them, was a Mr. BACON. A leafe of the furrounding country, fo far as the mines extended, was granted to him for the term of 99 years, at the yearly rent of two hundred pounds. Having the command of an extenfive capital, he immediately built forges, and began the manufacture of iron. But it happened in this, as it has in many great undertakings, that the first promoter reaped very little benefit from his new fpeculations. Mr. BACON, whether from mifmanagement, or fome other unavoidable caufe, fucceeded fo ill, that the works were for fome time entirely ftopped. It is likely the want of water-carriage from Myrther to the diftant fea ports, enhanced fo much the price of the goods, that they could not be brought cheap enough to market to enfure any great demand. The advantage, however, of pur. fuing the undertaking appeared fo manifeft, that it was not long before the heirs of Mr. BACON, who foon after his failure died, let one part of the diftrict to a Mr. CRAWSHAY, of London, for the yearly rent of five thousand pounds. This gentleman had a commanding capital of feventy thousand pounds to begin with; but faw clearly, that the most could not be made of the natural advantages of the place without the benefit of water conveyance for his goods. To form, however, a canal in a mountainous country was no eafy taik; yet, this difficulty was overcome by the perfevering genius of Mr. CRAWSHAY. In one inftance, fortune feemed to favour the fcheme, by a difcontinuity at the top of a lofty hill; without which advantage the canal would never have been undertaken.

Another part of the district is let to Mr. HOMFRAY, for two thoufand a year; a third part was taken by Meffrs. LEWIS and TATE; and the fourth, and laft, by Mr. HILL. Each of thefe gentlenen employs feveral forges, which, in their ftructure, look like the gloomy caftles of for

mer days, and give a very romantic appearance to the valley.

Hardly any thing can be conceived more awfully grand than the defcent, on a dark night, into the vale of Myrther, from any of the furrounding hills. On a fudden the travelier beholds numberless volcanos breathing out their undulating pillars of flame and finoke, while the furnaces below emit through every aperture a vivid light; the whole country feems in a blaze-nor do the immenfe hammers, the wheels, the rolling-mills, and the water-works, uniting together their various founds, add a little to the novelty and magnificence of the scene. When firft I beheld it, I almoft fancied myself approaching the Liparea Taberna of Vulcan; defcribed by Virgil fo beautifully in the eighth book of his Æneid. Infula Sicanium juxta latus Æoliamque Erigitur Lipara fumantibus ardua faxis: Quam fubter fpecus et Cyclopum exefa caminis Antra Ætnæa tonant, validique incudibus ictus

Auditi referunt gemitum, ftriduntque caver

nis

Stricturæ calybum et fornacibus ignis anhelat; Vulcani domus et Vulcania nomine tellus.

To Mr. CRAWSHAY are the public indebted for thus reviving, in a degree, the commercial confequence of this country, by a fuccefsful developement of its hidden treasures. The workmen belonging to him alone amount to between two and three thoufand men. An equal number is fuppofed to be employed by the other iron-malters. The whole population of the town is eftimated at 10,000 perfons.

Numberlefs are the benefits accruing to the furrounding parts from the re-eftablifhment of this manufacture: the old roads are improved and new ones formed; extenfive markets are opened for every kind of produce; and cultivation is extended to the tops of the highest hills.

It is now in agitation to make a dramroad from Myrther to Cardiff; a distance of about twenty miles. This kind of road is an improvement on rail-roads, which are pretty generally known. Its excellence chiefly confifts in having a wide groove for the wheels to run in, by which means the lateral friction is confiderably diminished, and the weight drawn eafier along. Its coft is estimated at thirty thousand pounds. A canal for the fame diftance has already coft one hundred thoufand; and this the new projected road is meant to fupercede. If upon trial it fhould be found to answer, might not fuch roads be established all over the kingdom?

and

and would not then the mail-coaches, and every other, travel much more fafely and expeditiously? Future times may probably fee this improvement.

Mr. CRAWSHAY is, perhaps, the greateft commercial adventurer, and at the fame time the moft fuccefsful, of any in the kingdom. He prides himself in having begun life without a fixpence; yet, by addrefs and induftry, raifing a princely fortune, and becoming the first iron-mafter in the world.

It is rather remarkable, that the famous WILKINSON fhould have fet off at firft under fimilar circumstances-in a fimilar line-and meet, at last, with nearly fimilar fuccefs. The plebeian metal feems aufpicious to plebeians.

Every thing that Mr. CRAWSHAY undertakes is carried on with a peculiar degree of fpirit. An overfhot-wheel has lately been conftructed by him, beyond compare, the largest in the world: it is above fifty feet in diameter; made entirely of caft iron, and coft four thoufand pounds. The water that turns it is brought from a ftream in the hills about five miles off, on a platform of wood, fupported chiefly by ftone pillars: in one part, however, where it croffes a bridge, it has fupporters of wood; here, for the fpace of three hundred yards, it is elevated eighty feet above the bed of the river. This forms a very fingular and fublime appearance. It is hardly worth mentioning, but as a trait of a remarkable character, that Mr. CRAWSHAY lately attempted to eftablish a porpoife fishery in the river Severn; but his ufual fuccels did not attend this undertaking. The fish were found too large to be taken. in a net, and too fmall to be harpooned; in a fhort time, therefore, and after fome trifling expence, this fcheme was abandoned.

I am, Sir, &c. A. B.

To the Editor of the Monthly Magazine. SIR,

OU know very well, that the preju

Y dice amongst the lower claffes of people against the inclofure of commons is very powerful and is almoft univerfal. It is idle to talk to fuch perfons about the general advantages to fociety which muft neceffarily refult from converting an uncultivated heath into an arable farm; they tell you that their portion of thofe advantages will be imperceptibly fmall, that a bird in the hand is worth two in the bu; that they relinquish a certain and immediate good for one that is diftant and

precarious. If you retort, that they deceive themselves refpecting the benefits which they derive from a common, and tell them that the hours which their wife and children wafte in wandering about for a few fticks or a bunch of furze, might be more profitably employed at home; or if you tell them, (as has been afferted in one of the county reports for the board of agriculture) that if one man turns a cow upon a common in the fpring of the year for nothing, and his neighbour gives eighteen pence a week to fome farmer for keeping in his inclofure another cow of equal value; that when both are driven to market at Michaelmas, the difference of price will more than reimburse the latter for his expence, befides the additional quantity of milk which his cow will yield, in confequence of her better food, they will laugh at your reafoning, deny the truth of your statement, and, like many wifer people, as they fancy themselves, prefer living in their error to running the risk of being undeceived to their cost.

For my own part, I have always thought it rather unfeeling to make arguments for other people, and afterwards act upon them whether they admit their validity or not: what folly it is to tell thofe poor creatures that the benefits they derive from a common are merely ideal, and therefore not worth attending to! and what cruelty it is on this account to make them relinquish their imaginary benefits, and force our own on them in exchange who is prepared to ftate the precife difference between a real and imaginary benefit? In fhort, what imaginary benefit is not real to him who enjoys it? See the blind beggar dance, the cripple fing, The fot a hero, lunatic a king. The ftarving chemift in his golden views Supremely bleft, the poet in his muse.

From what fountain flows the ftream of happiness more copioufly than imagination? But I am wandering I know not whither. What I mean to obferve is, that we ought to give the poor cottagers fomething more fubftantial in exchange for the benefits, whether they be called

real or imaginary, which they derive from their common, than the hope of participating with the mafs of fociety in the general advantage which will result from the inclofure. That I am not fingular in this opinion, is evident from the claufes which have been inferted in various private inclofure bills for the extra provifion of finall proprietors: thefe are of different natures, according to circumflances and fituations. Being myself at prefent concerned in the inclosure of a

common,

« PreviousContinue »